使用DataFrame.unstack的重塑，只有必要时创建计数器通过GroupBy.cumcount，第二级上次更改排序和按列扁平化多指标map：
df = (df.set_index(['stores', df.groupby('stores').cumcount().add(1)])
.unstack()
.sort_index(axis=1, level=1))
df.columns = df.columns.map('{0[0]}_{0[1]}'.format)
df = df.reset_index()
print (df)
stores discount_1 product_1 discount_2 product_2 discount_3 \
0 City of London T 102141.0 F 102142.0 T
1 Westminster T 102141.0 F 102142.0 NaN
product_3
0 102143.0
1 NaN
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