您可以先使用loc来查找nan该ids列中所有具有的行，然后使用at将它们的值设置为空列表来遍历这些行：
for row in df.loc[df.ids.isnull(), 'ids'].index:
df.at[row, 'ids'] = []
>>> df
date ids
0 2011-04-23 [0, 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13]
1 2011-04-24 [0, 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13]
2 2011-04-25 [0, 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13]
3 2011-04-26 []
4 2011-04-27 [0, 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13]
5 2011-04-28 [0, 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13]
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