首先，我将的较低值转换df为NaNbywhere和numpy.triuandstack，reset_index然后设置列名称：
import numpy as np
print df
a b c
a 1.0 0.5 0.3
b 0.5 1.0 0.4
c 0.3 0.4 1.0
print np.triu(np.ones(df.shape)).astype(np.bool)
[[ True True True]
[False True True]
[False False True]]
df = df.where(np.triu(np.ones(df.shape)).astype(np.bool))
print df
a b c
a 1 0.5 0.3
b NaN 1.0 0.4
c NaN NaN 1.0
df = df.stack().reset_index()
df.columns = ['Row','Column','Value']
print df
Row Column Value
0 a a 1.0
1 a b 0.5
2 a c 0.3
3 b b 1.0
4 b c 0.4
5 c c 1.0
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